Thermodynamics of Ionization of Benzoic Acid and Some Substituted Benzoic Acids in 1,4-Dioxane--Water Mixtures.
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چکیده
منابع مشابه
Acoustical Studies of Some Derivatives of 4-Amino Benzoic Acid in 1, 4-Dioxane and Dimethyl Formamide at 308.15 K
The ultrasonic velocity, density and viscosity of some Schiff bases of 4-amino benzoic acid were measured in 1,4-dioxane and dimethylformamide at 308.15 K. Various acoustical properties such as isentropic compressibility (ks), Rao’s molar sound function (Rm), the Van der Waals constant (b), molar compressibility (W), inter molecular free len...
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It has been observed in this laboratory (15) that the normally polar distribution of callus growth on tobacco stem explants becomes non-po'ar in the presence of low levels of 2,3,5-triiodobenzoic acid (TIBA), while the amount of callus growth is not diminished. It was thought that this phenomenon might reflect a specific inhibition by TIBA of the polar transport of auxin. Subsequent studies (10...
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The microwave spectrum of the mono-fluoro-benzoic acids, 2-fluoro-, 3-fluoro-, and 4-fluoro-benzoic acid have been measured in the frequency range of 4-14 GHz using a pulsed beam Fourier transform microwave spectrometer. Measured rotational transition lines were assigned and fit using a rigid rotor Hamiltonian. Assignments were made for 3 conformers of 2-fluorobenzoic acid, 2 conformers of 3-fl...
متن کاملApplication of Hammett Constant for Prediction of Acidity Properties of Substituted Benzoic Acid
Hammett constants (σ) can be important factor to understanding substitution and position effects on benzoic acid. This report describes a computational study of ∆G◦ and σ for six substituted benzoic acid (X= F,Cl ,OH ,NH2 ,CN,NO2 )and phenylacetic acid substituted (X=OH ,NH2 ) at para and meta positions ingas and aqueousphases by DFT method and comparesit to available experimental and theoretic...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1992
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.46-0399